4-Chloro-2-methyl-N-(4-methylphenyl)benzenesulfonamide
نویسندگان
چکیده
The asymmetric unit of the title compound, C(14)H(14)ClNO(2)S, contains two independent mol-ecules. The torsion angles of the C-SO(2)-NH-C segments in the two mol-ecules are -76.5 (5) and -48.3 (4)°. The two aromatic rings are tilted relative to each other by 76.6 (2)° in one mol-ecule and 70.7 (2)° in the other. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers.
منابع مشابه
4-Chloro-2-methyl-N-(2-methylphenyl)benzenesulfonamide
In the crystal structure of the title compound, C(14)H(14)ClNO(2)S, the two aromatic rings are tilted relative to each other by 45.8 (1)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
متن کامل4-Chloro-2-methyl-N-(3-methylphenyl)benzenesulfonamide
The N-H bond in the title compound, C(14)H(14)ClNO(2)S, the dihedral angle between the two benzene rings is 75.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل4-Chloro-N-(3-methylphenyl)benzenesulfonamide
In the crystal of the title compound, C(13)H(12)ClNO(2)S, the N-H bond is anti to the meta-methyl group in the aniline ring. The C-SO(2)-NH-C torsion angle is -57.6 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 84.7 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کاملN-(2-Methylphenyl)benzenesulfonamide
In the title compound, C(13)H(13)NO(2)S, the conformation of the N-H bond is anti to the ortho-methyl group on the aniline ring, in contrast to the syn conformation observed with respect to the ortho-chloro group in N-(2-chloro-phen-yl)benzene-sulfonamide. The dihedral angle between the two benzene rings is 61.5 (1)°. Mol-ecules are linked into chains running along the a axis by N-H⋯O hydrogen ...
متن کامل4-Methyl-N-(2-methylphenyl)benzenesulfonamide
In the title compound, C(14)H(15)NO(2)S, the dihedral angle between the aromatic rings is 49.7 (1)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
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